Product ID:9967, VANADIUM REFERENCE STANDARD SOLUTION(SUPDAT)
MSDS Date:04/12/1991
FSC:6810
NIIN:00N056722
MSDS Number: CDWLN

FISHER SCIENTIFIC CO

1 REAGENT LN
FAIR LAWN, NJ 07410-2802
US

Emergency Phone: 201-796-7100;800-424-9300(CHEMTREC)

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA 302/313)

CAS: 7647-01-0

RTECS: MW4025000

Fraction By Weight: 6.1%

OSHA PEL C 5 PPM

ACGIH TLV: C 5 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VANADIUM PENTOXIDE (SARA 302) (CERCLA)

CAS: 1314-62-1

RTECS: YW2450000

Fraction By Weight: 0.16%

OSHA PEL C,0.5 MG/M3

ACGIH TLV: 0.05 MG/M3 RDUST

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 93.7%

OSHA PEL N/K

ACGIH TLV: N/K

DO NOT USE WATER

RTECS: 9999999ZZ

USE WATER SPRAY/FOG IN FLOODING AMTS. USE WATER SPRAY

RTECS: 9999999ZZ

WATER FROM AS FAR A DIST AS POSS. AVOID BREATHING

RTECS: 9999999ZZ

SPECIFIC INFORMATION CONTACT NEHC .

RTECS: 9999999ZZ

INFLAMM, ULCERATION, NECROSIS & CHEM BURNS.

RTECS: 9999999ZZ

COLLAPSE. PHOTOSENSIT RXNS MAY OCCUR IN PERSONS

RTECS: 9999999ZZ

CONT MAY CAUSE SEV IRRIT, CONJ,

RTECS: 9999999ZZ

DROP OF HYDROCHLORIC ACID SPLASHED IN EYE & IMMED

RTECS: 9999999ZZ

CONJ EPITHELIUM. ANIMALS EXPOS TO VAP CONCS OF 1350

RTECS: 9999999ZZ

FOR 6 HRS SHOWED SLIGHT EROSION OF CORNEAL

RTECS: 9999999ZZ

ACID MAY CAUSE BURNS OF MOUTH, THROAT, ESOPHAGUS &

RTECS: 9999999ZZ

VOMIT, DIARR, CHILLS, SHOCK & INTENSE THRIST,

RTECS: 9999999ZZ

CIRCULATORY COLLAPSE MAY OCCUR. DEATH MAY BE DUE TO

RTECS: 9999999ZZ

PRLNGD EXPOS MAY CAUSE EROSION & DISCOLORATION OF

RTECS: 9999999ZZ

PRLNGD CONT W/VAPS/DILUTE SOLNS MAY CAUSE DERM.

RTECS: 9999999ZZ

FOR 6 HRS DAILY FOR 50 DAYS SHOWED ONLY SLIGHT

RTECS: 9999999ZZ

DEPENDENT UPON CONC & DURATION OF EXPOS. CONJ/EFTS

RTECS: 9999999ZZ

SKIN CONTACT WITH THIS SUBSTANCE.

RTECS: 9999999ZZ

100 FOLD TO RENDER IT HARMLESS TO TISSUES.

RTECS: 9999999ZZ

POISONING, 12TH ED.). GET MED ATTN IMMED. IF VOMIT

RTECS: 9999999ZZ

NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:GAS/FUMES @ LEVELS OF 5-35
PPM MAY CAUSE IRRIT & BURNING OF THROAT, COUGH & CHOKING; 50-100
PPM MAY BE BARELY TOLERABLE FOR 1 HR. HIGH LEVELS MAY CAUSE INFLAMM
& OCCASNLY ULCERATION OF NOS E, THROAT/LARYNX, BRONCH, PNEUM,
PALPITATIONS & HDCH. HIGHER CONCS MAY CAUSE NECROSIS OF TRACHEA, &
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:BRONCH EPITHELIUM, NASOSEPTAL
PERFORATION, ATELECTASIS, EMPHYSEMA, DMG TO PULM BLOOD VESS &
LESIONS OF LIVER & OTHER ORGANS. DEATH MAY BE DUE TO LARYNGEAL
SPASM, BRONCHOPNEUM/PULM EDEMA. 1300 -2000 PPM MAY BE DANGEROUS
EVEN ON BRIEF EXPOS. REPROD EFTS RPTD IN ANIMALS. SKIN:MAY CAUSE
SEV IRRITATION,(ING 8)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE OXYG/ARTF
RESP) . EYES:IMMED FLUSH W/POTABLE WATER FOR @ LST 15 MIN, SEEK
ASSISTANCE FROM MD . SKIN:FLUSH W/COPIOUS AMTS OF WATER. CALL MD (F
P N). INGEST:DO NOT USE GASTRIC LAVAGE/EMESIS. DILUTE ACID IMMED BY
DRINKING LG QTYS OF WATER/MILK. IF VOMIT PERSISTS, ADMIN FLUIDS
REPEATEDLY. INGESTED ACID MUST BE DILUTED APPROXIMATELY (ING 22)

Extinguishing Media:DRY CHEM, CO*2, WATER SPRAY/REGULAR FOAM. LGR
FIRES, USE WATER SPRAY, FOG/REGULAR FOAM (1990 EMER RESPONSE
(SUPDAT)
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.

Spill Release Procedures:OCCUPATIONAL SPILL:COVER WITH SODA ASH. SCOOP
UP AND PLACE IN A SUITABLE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:PROVIDE LOCAL EXHAUST/PROCESS ENCLOSURE VENT TO MEET
PUBLISHED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 25)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT POSSIBILITY OF (ING
21)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE NAME/PART NO:1000 PPM. EXTING MEDIA:GUIDEBOOK, DOT P 5800.5).
MOVE CNTNR FROM FIRE AREA IF CAN BE DONE W/OUT RISK. APPLY COOLING
WATER TO SIDES OF CNTNRS THAT ARE EXPOS TO FLAMES UNTIL WELL AFTER
FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS (1990 EMER RESPONSE
GUIDEBOOK, DOT P 5800.5, GUIDE PAGE 601. (ING 4)

Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Vapor Pres:14 @ 20C
Vapor Density:0.7 (H*2O)
Spec Gravity:1.0
Evaporation Rate & Reference:>1 (ETHER =1)
Solubility in Water:COMPLETELY
Appearance and Odor:GREEN-YELLOW LIQUID.

Stability Indicator/Materials to Avoid:YES
ACETIC ANHYDROIDE, ALCOHOLIC HYDROGEN CYANIDE, ALUMINUM,
ALUMINIUM-TITANIUM ALLOYS, 2-AMINOETHANOL. FOR MORE (ING 7)
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
CORROSIVE HYDROGEN CHLORIDE.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.